Key Laboratory of Eco-Environment-Related Polymer Materials Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China.
J Org Chem. 2012 Sep 21;77(18):8310-6. doi: 10.1021/jo300827s. Epub 2012 Sep 10.
Triarylaminium salt was disclosed as an efficient initiator for the novel Friedel-Crafts alkylation/annulation cascade reaction between chalcone epoxides and 2-naphthols to construct polysubstituted 1,2-dihydronaphtho[2,1-b]furans. The DDQ/NaNO(2)/O(2) catalytic system was first applied to the aerobic oxidative aromatization of heterocycles, and a simple and efficient one-pot tandem FC alkylation/annulation/aerobic oxidative aromatization procedure was also developed for the synthesis of complex naphtho[2,1-b]furans.
三芳基鏻盐被披露为一种有效的引发剂，用于新型 Friedel-Crafts 烷基化/环化级联反应，该反应在查尔酮环氧化物和 2-萘酚之间进行，以构建多取代的 1,2-二氢萘并[2,1-b]呋喃。DDQ/NaNO2/O2 催化体系首次应用于杂环的有氧氧化芳构化，并且还开发了一种简单有效的一锅串联 FC 烷基化/环化/有氧氧化芳构化程序，用于合成复杂的萘并[2,1-b]呋喃。
