Research Laboratories in Sciences Applied to Food, Canadian Irradiation Centre (CIC), INRS-Institut Armand-Frappier, University of Quebec, 531 Boulevard des Prairies, Laval, Québec, H7V 1B7, Canada.
Carbohydr Polym. 2012 Nov 6;90(4):1757-63. doi: 10.1016/j.carbpol.2012.07.065. Epub 2012 Aug 1.
Nanocrystalline cellulose (NCC) reinforced alginate-based nanocomposite film was prepared by solution casting. The NCC content in the matrix was varied from 1 to 8% ((w/w) % dry matrix). It was found that the nanocomposite reinforced with 5 wt% NCC content exhibits the highest tensile strength which was increased by 37% compared to the control. Incorporation of NCC also significantly improved water vapor permeability (WVP) of the nanocomposite showing a 31% decrease due to 5 wt% NCC loading. Molecular interactions between alginate and NCC were supported by Fourier Transform Infrared Spectroscopy. The X-ray diffraction studies also confirmed the appearance of crystalline peaks due to the presence of NCC inside the films. Thermal stability of alginate-based nanocomposite films was improved after incorporation of NCC.
纳米纤维素(NCC)增强的海藻酸钠基纳米复合材料薄膜通过溶液浇铸法制备。基体中 NCC 的含量从 1%变化到 8%((干基体的)(w/w)%)。结果发现,增强 5wt%NCC 含量的纳米复合材料具有最高的拉伸强度,与对照相比增加了 37%。NCC 的加入也显著提高了纳米复合材料的水蒸气透过率(WVP),由于 5wt%NCC 的加入,WVP 降低了 31%。傅里叶变换红外光谱支持海藻酸钠和 NCC 之间的分子相互作用。X 射线衍射研究也证实了由于薄膜内部存在 NCC,出现了结晶峰。NCC 的加入提高了海藻酸钠基纳米复合材料薄膜的热稳定性。