Department of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9804-8. doi: 10.1002/anie.201202992. Epub 2012 Sep 3.
Single-molecule trap: Easy activation of the water-stable metal-organic framework PCN-200 provides a new route to low-energy selective CO(2) capture through stimuli-responsive adsorption behavior. This elastic CO(2) trapping effect was confirmed by single-component and binary gas-adsorption isotherms and crystallographic determination.
易于激活的水稳定金属有机骨架 PCN-200 通过刺激响应吸附行为提供了一种低能耗选择性 CO(2)捕获的新途径。这种弹性 CO(2)捕获效应通过单组分和二元气体吸附等温线和晶体学测定得到了证实。