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负载五氧化二钒(V2O5)的二氧化钛纳米粒子的可见光诱导杀菌活性。

Visible-light-induced bactericidal activity of vanadium-pentoxide (V2O5)-loaded TiO2 nanoparticles.

机构信息

Environment Division, Korea Institute of Science and Technology (KIST), 39-1, Hawolgok, Seongbuk, Seoul, Republic of Korea.

出版信息

Appl Biochem Biotechnol. 2012 Nov;168(5):1143-52. doi: 10.1007/s12010-012-9847-9. Epub 2012 Sep 5.

Abstract

The bactericidal activity of TiO(2) nanoparticles under visible light is very important in regards to its practical applications. In this paper, we synthesized vanadium-pentoxide-loaded TiO(2) nanoparticles (V(2)O(5)-TiO(2)) using a chemical vapor condensation method, followed by the impregnation method, and characterized its physicochemical properties through X-ray diffraction patterning, X-ray photoelectron spectroscopy analysis, Raman spectra analysis, and Fourier transform infrared analysis. In addition, the antibacterial activity of V(2)O(5)-TiO(2) nanoparticles against E. coli was evaluated and compared with pure TiO(2) nanoparticles. In these experiments, the population of E. coli was shown to be significantly reduced by V(2)O(5)-TiO(2) nanoparticles under illumination with fluorescent light, whereas pure TiO(2) nanoparticles showed about 3.3-fold lower antibacterial activity than the V(2)O(5)-TiO(2) nanoparticles. This result was most likely due to the change in surface conditions of the TiO(2) nanoparticles, which was due to the loading of vanadium pentoxide on the TiO(2) nanoparticles. Furthermore, both photocatalysts showed similar antibacterial activity under UV-A (352 nm) irradiation.

摘要

TiO2 纳米粒子在可见光下的杀菌活性对于其实际应用非常重要。本文采用化学气相冷凝法合成了负载五氧化二钒的 TiO2 纳米粒子(V2O5-TiO2),然后采用浸渍法,通过 X 射线衍射图、X 射线光电子能谱分析、拉曼光谱分析和傅里叶变换红外分析对其物理化学性质进行了表征。此外,还评估了 V2O5-TiO2 纳米粒子对大肠杆菌的抗菌活性,并与纯 TiO2 纳米粒子进行了比较。在这些实验中,在荧光灯下照射时,V2O5-TiO2 纳米粒子显著降低了大肠杆菌的数量,而纯 TiO2 纳米粒子的抗菌活性比 V2O5-TiO2 纳米粒子低约 3.3 倍。这一结果很可能是由于 TiO2 纳米粒子表面条件发生了变化,这是由于负载在 TiO2 纳米粒子上的五氧化二钒。此外,两种光催化剂在 UV-A(352nm)照射下都表现出相似的抗菌活性。

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