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粉煤灰基地聚物再生混凝土的力学性能与微观结构分析。

Mechanical properties and microstructure analysis of fly ash geopolymeric recycled concrete.

机构信息

College of Architecture and Environment, Sichuan University, Chengdu, PR China.

出版信息

J Hazard Mater. 2012 Oct 30;237-238:20-9. doi: 10.1016/j.jhazmat.2012.07.070. Epub 2012 Aug 25.

Abstract

Six mixtures with different recycled aggregate (RA) replacement ratios of 0%, 50% and 100% were designed to manufacture recycled aggregate concrete (RAC) and alkali-activated fly ash geopolymeric recycled concrete (GRC). The physical and mechanical properties were investigated indicating different performances from each other. Optical microscopy under transmitted light and scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDX) were carried out in this study in order to identify the mechanism underlying the effects of the geopolymer and RA on concrete properties. The features of aggregates, paste and interfacial transition zone (ITZ) were compared and discussed. Experimental results indicate that using alkali-activated fly ash geopolymer as replacement of ordinary Portland cement (OPC) effectively improved the compressive strength. With increasing of RA contents in both RAC and GRC, the compressive strength decreased gradually. The microstructure analysis shows that, on one hand, the presence of RA weakens the strength of the aggregates and the structure of ITZs; on the other hand, due to the alkali-activated fly ash in geopolymer concrete, the contents of Portlandite (Ca(OH)(2)) and voids were reduced, as well as improved the matrix homogeneity. The microstructure of GRC was changed by different reaction products, such as aluminosilicate gel.

摘要

设计了 6 种不同再生骨料(RA)替代率(0%、50%和 100%)的混合物来制造再生骨料混凝土(RAC)和碱激活粉煤灰地质聚合物再生混凝土(GRC)。研究了它们的物理力学性能,结果表明彼此之间具有不同的性能。为了研究地质聚合物和 RA 对混凝土性能的影响机理,本研究进行了透反射光显微镜观察和扫描电子显微镜(SEM)结合能谱分析(EDX)。比较和讨论了骨料、浆体和界面过渡区(ITZ)的特征。实验结果表明,用碱激活粉煤灰地质聚合物替代普通波特兰水泥(OPC)可有效提高抗压强度。随着 RAC 和 GRC 中 RA 含量的增加,抗压强度逐渐降低。微观结构分析表明,一方面,RA 的存在削弱了骨料的强度和 ITZ 的结构;另一方面,由于地质聚合物混凝土中的碱激活粉煤灰,减少了 Portlandite(Ca(OH)(2))和空隙的含量,同时提高了基质的均匀性。GRC 的微观结构因不同的反应产物(如铝硅酸盐凝胶)而发生变化。

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