Department of Civil and Environmental Engineering, University of Illinois, 205 North Mathews Avenue, Urbana, Illinois 61801, USA.
Environ Sci Technol. 2012 Oct 16;46(20):11305-12. doi: 10.1021/es303099t. Epub 2012 Oct 5.
Electrothermal swing adsorption (ESA) of organic compounds from gas streams with activated carbon fiber cloth (ACFC) reduces emissions to the atmosphere and recovers feedstock for reuse. Local temperature measurement (e.g., with a thermocouple) is typically used to monitor/control adsorbent regeneration cycles. Remote electrical resistance measurement is evaluated here as an alternative to local temperature measurement. ACFC resistance that was modeled based on its physical properties was within 10.5% of the measured resistance values during electrothermal heating. Resistance control was developed based on this measured relationship and used to control temperature to within 2.3% of regeneration set-point temperatures. Isobutane-laden adsorbent was then heated with resistance control. After 2 min of heating, the temperature of the adsorbent with isobutane was 13% less than the adsorbent without isobutane. This difference decreased to 2.1% after 9 min of heating, showing desorption of isobutane. An ACFC cartridge was also heated to 175 °C for 900 cycles with its resistance and adsorption capacity values remaining within 3% and 2%, respectively. This new method to control regeneration power application based on rapid sensing of the adsorbent's resistance removes the need for direct-contact temperature sensors providing a simple, cost-efficient, and long-term regeneration technique for ESA systems.
用电热式吸附(ESA)从气流中用活性炭纤维布(ACFC)吸附有机化合物可以减少向大气中的排放,并回收原料以重复使用。通常使用局部温度测量(例如热电偶)来监测/控制吸附剂的再生循环。这里评估了远程电阻测量作为局部温度测量的替代方法。基于其物理特性对 ACFC 电阻进行建模,在电热加热过程中,其电阻值与实测值相差在 10.5%以内。根据这一测量关系开发了电阻控制,用于将温度控制在再生设定点温度的 2.3%以内。然后用电阻控制加热负载异丁烷的吸附剂。加热 2 分钟后,负载异丁烷的吸附剂温度比没有异丁烷的吸附剂低 13%。加热 9 分钟后,这种差异减小到 2.1%,表明异丁烷解吸。还对一个 ACFC 筒进行了 175°C 加热 900 次,其电阻和吸附容量值分别保持在 3%和 2%以内。这种基于快速感应吸附剂电阻的再生功率施加控制的新方法,无需直接接触式温度传感器,为 ESA 系统提供了一种简单、经济高效且长期的再生技术。