Department of Civil and Environmental Engineering, University of Illinois, Urbana, Illinois 61801, USA.
Environ Sci Technol. 2011 Jan 15;45(2):738-43. doi: 10.1021/es103303f. Epub 2010 Dec 15.
Electrothermal swing adsorption (ESA) of organic gases generated by industrial processes can reduce atmospheric emissions and allow for reuse of recovered product. Desorption energy efficiency can be improved through control of adsorbent heating, allowing for cost-effective separation and concentration of these gases for reuse. ESA experiments with an air stream containing 2000 ppm(v) isobutane and activated carbon fiber cloth (ACFC) were performed to evaluate regeneration energy consumption. Control logic based on temperature feedback achieved select temperature and power profiles during regeneration cycles while maintaining the ACFC's mean regeneration temperature (200 °C). Energy requirements for regeneration were independent of differences in temperature/power oscillations (1186-1237 kJ/mol of isobutane). ACFC was also heated to a ramped set-point, and the average absolute error between the actual and set-point temperatures was small (0.73%), demonstrating stable control as set-point temperatures vary, which is necessary for practical applications (e.g., higher temperatures for higher boiling point gases). Additional logic that increased the maximum power application at lower ACFC temperatures resulted in a 36% decrease in energy consumption. Implementing such control logic improves energy efficiency for separating and concentrating organic gases for post-desorption liquefaction of the organic gas for reuse.
工业过程中产生的有机气体的电热式变吸附(ESA)可以减少大气排放,并允许回收产品的再利用。通过控制吸附剂加热,可以提高解吸能量效率,从而实现这些气体的经济高效分离和浓缩,以进行再利用。进行了含有 2000ppm(v) 异丁烷和活性炭纤维布(ACFC)的空气流的 ESA 实验,以评估再生能耗。基于温度反馈的控制逻辑在再生循环期间实现了选择的温度和功率曲线,同时保持 ACFC 的平均再生温度(200°C)。再生的能量需求与温度/功率振荡的差异无关(1186-1237 kJ/mol 异丁烷)。还将 ACFC 加热到斜坡设定点,实际温度和设定点温度之间的平均绝对误差较小(0.73%),表明在设定点温度变化时具有稳定的控制,这对于实际应用是必要的(例如,对于较高沸点的气体,较高的温度)。在 ACFC 温度较低时增加最大功率应用的附加逻辑导致能耗降低了 36%。实施这种控制逻辑可以提高分离和浓缩有机气体的能量效率,以便对有机气体进行解吸后液化再利用。