Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208, United States.
J Magn Reson. 2012 Oct;223:80-4. doi: 10.1016/j.jmr.2012.07.023. Epub 2012 Aug 8.
The rapidly-changing magnetic field of sinusoidal rapid scans creates background signals that are dominated by oscillations at the scan frequency. The background oscillations can be removed without acquiring off-resonance data. For data acquired in quadrature, up-field and down-field scan signals can be separated in the frequency domain. For each scan direction, the background oscillation can be calculated by fitting to the half cycle that does not contain the EPR signal. The extrapolated fit function is then subtracted from the half cycle that contains the EPR signal. By zeroing the array for the half cycles that do not contain the EPR signal, the signal-to-noise is improved and the data are corrected for non-orthogonality of the quadrature channels.
正弦快速扫描的快速变化磁场会产生背景信号,这些信号主要由扫描频率处的振荡组成。可以在不获取失谐数据的情况下去除背景振荡。对于在正交模式下采集的数据,可以在频域中分离上磁场和下磁场扫描信号。对于每个扫描方向,可以通过拟合不包含 EPR 信号的半周期来计算背景振荡。然后,从包含 EPR 信号的半周期中减去外推拟合函数。通过对不包含 EPR 信号的半周期置零,提高了信噪比,并校正了正交通道的非正交性。