溶解的 LiCl 对离子液体-Au(111) 电双层结构的影响。
Effect of dissolved LiCl on the ionic liquid-Au(111) electrical double layer structure.
机构信息
Centre for Advanced Particle Processing, The University of Newcastle, Callaghan, NSW 2308, Australia.
出版信息
Chem Commun (Camb). 2012 Oct 21;48(82):10246-8. doi: 10.1039/c2cc35737b.
PMID:22968524
Abstract
The electrical double layer at ionic liquid (IL)-Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between -2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.
摘要
在离子液体 (IL)-Au(111) 界面处的双电层由交替的离子层组成。当少量 LiCl 溶解在 IL 中时，所有介于 -2.0 V 和 +2.0 V（相对于 Pt）之间的电位下，界面分层明显减弱。这意味着当存在溶质时，为纯 IL 双电层开发的模型可能无效。
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