用于醛和未活化酮的空间控制氢膦酰化反应的高效碱土催化剂。 - Suppr

Highly effective alkaline earth catalysts for the sterically governed hydrophosphonylation of aldehydes and nonactivated ketones.

作者信息

Liu Bo, Carpentier Jean-François, Sarazin Yann

机构信息

Organometallics: Materials and Catalysis, Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France.

出版信息

Chemistry. 2012 Oct 15;18(42):13259-64. doi: 10.1002/chem.201201489. Epub 2012 Sep 13.

DOI:10.1002/chem.201201489

PMID:22976437

Abstract

摘要

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Highly effective alkaline earth catalysts for the sterically governed hydrophosphonylation of aldehydes and nonactivated ketones.用于醛和未活化酮的空间控制氢膦酰化反应的高效碱土催化剂。

Chemistry. 2012 Oct 15;18(42):13259-64. doi: 10.1002/chem.201201489. Epub 2012 Sep 13.

Alkaline earth metal catalysts for asymmetric reactions.用于不对称反应的碱土金属催化剂。

Acc Chem Res. 2011 Jan 18;44(1):58-71. doi: 10.1021/ar100101b. Epub 2010 Oct 27.

Bis(trimethylsilyl)methyl derivatives of calcium, strontium and barium: potentially useful dialkyls of the heavy alkaline earth elements.钙、锶和钡的双（三甲基硅基）甲基衍生物：重碱土金属元素潜在有用的二烷基化合物。

Chemistry. 2008;14(36):11292-5. doi: 10.1002/chem.200801957.

Heavier alkaline Earth amides as catalysts for the Tischenko reaction.较重的碱土金属酰胺作为蒂申科反应的催化剂。

Org Lett. 2007 Jan 18;9(2):331-3. doi: 10.1021/ol0627247.

Highly efficient hydrophosphonylation of aldehydes and unactivated ketones catalyzed by methylene-linked pyrrolyl rare earth metal amido complexes.偕二甲基吡咯基稀土金属酰胺配合物催化的醛和未活化酮的高效氢膦酰化反应。

Chemistry. 2012 Feb 27;18(9):2653-9. doi: 10.1002/chem.201102207. Epub 2012 Jan 19.

The crystal chemistry of the alkaline-earth apatites A(10)(PO(4))(6)Cu(x)O(y)(H)(z) (A = Ca, Sr and Ba).碱土金属磷灰石A(10)(PO(4))(6)Cu(x)O(y)(H)(z)（A = 钙、锶和钡）的晶体化学

Dalton Trans. 2009 Sep 14(34):6722-6. doi: 10.1039/b906639j. Epub 2009 Jun 17.

Addition reactions of sulfonylimidates with imines catalyzed by alkaline earth metals.碱土金属催化的磺酰亚氨酸酯与亚胺的加成反应。

Angew Chem Int Ed Engl. 2009;48(32):5927-9. doi: 10.1002/anie.200900309.

Lanthanide anilido complexes: synthesis, characterization, and use as highly efficient catalysts for hydrophosphonylation of aldehydes and unactivated ketones.镧系苯胺基配合物：合成、表征及其作为醛和未活化酮氢膦酰化高效催化剂的应用。

Dalton Trans. 2014 Jun 14;43(22):8355-62. doi: 10.1039/c4dt00522h.

n-BuLi as a highly efficient precatalyst for hydrophosphonylation of aldehydes and unactivated ketones.正丁基锂作为醛类和未活化酮类氢膦酰化反应的高效预催化剂。

Org Lett. 2014 Dec 5;16(23):6172-5. doi: 10.1021/ol5030713. Epub 2014 Nov 14.

A Green Approach for Allylations of Aldehydes and Ketones: Combining Allylborate, Mechanochemistry and Lanthanide Catalyst.醛和酮烯丙基化的绿色方法：烯丙基硼酸酯、机械化学与镧系催化剂的结合

Molecules. 2016 Nov 16;21(11):1539. doi: 10.3390/molecules21111539.

引用本文的文献

Unexpected Reaction of Dialkyl α-Hydroxy-benzylphosphonates with Dialkyl Phosphites and a Few Related Reactions.二烷基α-羟基苄基膦酸酯与亚磷酸二烷基酯的意外反应及一些相关反应

J Org Chem. 2025 Jan 10;90(1):439-447. doi: 10.1021/acs.joc.4c02355. Epub 2024 Dec 17.

Advances in heavy alkaline earth chemistry provide insight into complexation of weakly polarizing Ra, Ba, and Sr cations.重碱土化学的进展为弱极化镭、钡和锶阳离子的络合作用提供了见解。

Sci Adv. 2024 Jan 5;10(1):eadj8765. doi: 10.1126/sciadv.adj8765.

Synthesis and Reactions of α-Hydroxyphosphonates.α-羟基膦酸酯的合成与反应。

Molecules. 2018 Jun 20;23(6):1493. doi: 10.3390/molecules23061493.

NHCs catalyzed hydrophosphonylation of α-ketoesters and α-trifluoromethyl ketones.N-杂环卡宾催化α-酮酯和α-三氟甲基酮的氢膦酰化反应。

ScientificWorldJournal. 2013 Dec 31;2013:890187. doi: 10.1155/2013/890187. eCollection 2013.

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Highly effective alkaline earth catalysts for the sterically governed hydrophosphonylation of aldehydes and nonactivated ketones.

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