由钐二碘化物和电解介导的在交界处位置具有两个甲基的氢化茚酮的环化反应。
Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis.
机构信息
Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan.
出版信息
Molecules. 2012 Sep 13;17(9):11079-88. doi: 10.3390/molecules170911079.
Abstract
One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
摘要
三碘化钐介导的烯酮与酮或醛的单电子还原分子内环化反应，并通过电解得到顺式-三甲基-氢化茚满酮。反应的选择性范围从 1:1 到 100:0，具体取决于条件。
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