基于镧系有机配合物的杂化材料：综述。

Hybrid materials based on lanthanide organic complexes: a review.

机构信息

State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, People's Republic of China.

出版信息

Chem Soc Rev. 2013 Jan 7;42(1):387-410. doi: 10.1039/c2cs35069f. Epub 2012 Sep 13.

DOI:10.1039/c2cs35069f

PMID:22977887

Abstract

A great deal of research has been carried out on lanthanide organic complex-based organic-inorganic hybrid materials in the last decade. This critical review begins with a formulation of the fundamentals of lanthanide organic complex luminescence, and presents various current designed ideas, synthetic routes, luminescence behaviors and potentials of the latest advanced (a) sol-gel materials, (b) mesoporous materials, (c) titania materials, (d) ionic liquids and ionogels, (e) polymers, and (f) bifunctional magnetic-optical composites based on lanthanide organic complexes. Finally, challenges and opportunities for further improvement of organic-inorganic hybrid luminescent materials based on lanthanide organic complexes will be discussed.

摘要

过去十年中，人们对基于镧系有机配合物的有机-无机杂化材料进行了大量研究。本综述首先阐述了镧系有机配合物发光的基本原理，然后介绍了基于镧系有机配合物的最新先进（a）溶胶-凝胶材料、（b）介孔材料、（c）二氧化钛材料、（d）离子液体和离子凝胶、（e）聚合物和（f）双功能磁-光复合材料的各种设计思路、合成路线、发光行为和潜力。最后，讨论了进一步提高基于镧系有机配合物的有机-无机杂化发光材料性能所面临的挑战和机遇。