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铕配合物功能化玻璃纤维纸的合成及其荧光性能

Synthesis and fluorescence properties of europium complex functionalized fiberglass paper.

作者信息

Li Qiuping, Wen Qianqian, Fang Zian, Wang Yidi, Ouyang Hongxia, Wang Qi, Wei Meng

机构信息

FuZhou AI Drug Innovation Center, School of Pharmacy, Fuzhou Medical College of Nanchang University Fuzhou 344000 China

Jiangxi Yatai Technology Co., Ltd Yichun 336100 China.

出版信息

RSC Adv. 2024 Sep 20;14(41):30037-30044. doi: 10.1039/d4ra05143b. eCollection 2024 Sep 18.

Abstract

The development of novel rare earth fluorescent materials and the exploration of their applications have consistently been focal points of research in the fields of materials science and chemistry. In this work, a novel rare earth composite material with good photo-fluorescence properties and self-supporting has been prepared a simple ultrasonic solvent reaction method. Initially, the Phen moieties is immobilized onto the surface of a self-supporting fiberglass paper using ICPTES, followed by the coordination of Eu(TTA) moieties with Phen moieties through a convenient ultrasonic solvent reaction. The resulting GF-Phen-Eu(TTA) has been characterized using FTIR, UV-Vis DRS, fluorescence measurements, and so on. The results indicate that the composite material exhibits strong fluorescent emission and presents a vivid red color under ultraviolet light. Further research has shown that the fluorescence of GF-Phen-Eu(TTA) strips demonstrated a pronounced quenching effect in response to some transition metal ions (1 mM). Hence, the rare earth composite materials presented here can be utilized not only for the production of optical materials, but also for the development of fluorescence sensing strips.

摘要

新型稀土荧光材料的开发及其应用探索一直是材料科学和化学领域的研究重点。在这项工作中,通过一种简单的超声溶剂反应方法制备了一种具有良好光荧光性能且自支撑的新型稀土复合材料。首先,使用ICPTE将菲咯啉部分固定在自支撑玻璃纤维纸的表面,然后通过便捷的超声溶剂反应使铕(噻吩甲酰三氟丙酮)部分与菲咯啉部分配位。所得的GF-Phen-Eu(TTA)已通过傅里叶变换红外光谱(FTIR)、紫外可见漫反射光谱(UV-Vis DRS)、荧光测量等进行了表征。结果表明,该复合材料表现出强烈的荧光发射,在紫外光下呈现鲜艳的红色。进一步的研究表明,GF-Phen-Eu(TTA)条带的荧光对某些过渡金属离子(1 mM)表现出明显的猝灭效应。因此,这里展示的稀土复合材料不仅可用于生产光学材料,还可用于开发荧光传感条带。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90c8/11413861/28d862ead5d1/d4ra05143b-s1.jpg

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