Department of Chemical Engineering and Applied Chemistry, The University of Toronto, 200 College Street, Toronto, Ontario, Canada M5S 3E5.
ACS Appl Mater Interfaces. 2012 Oct 24;4(10):5055-68. doi: 10.1021/am3015197. Epub 2012 Sep 27.
Boron subphthalocyanines (BsubPcs) are an emerging class of high performing materials in organic electronics. Since the first use of chloroboron subphthalocyanine in an organic electronic device 6 years ago subphthalocyanines have shown potential as functional materials in organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs). Here we review the material properties of chloroboron subphthalocyanine (Cl-BsubPc) and its use as an organic semiconductor. We then highlight our efforts toward derivatives of boron subpthalocyanine beyond Cl-BsubPc and discuss the impact of molecular design on the material properties and the performance of the BsubPc. Finally, we comment on the status of BsubPcs in the field of organic electronics and discuss how we believe future progress can be made.
硼次酞菁（BsubPcs）是一类新兴的高性能有机电子材料。自从 6 年前氯代硼次酞菁首次应用于有机电子器件以来，次酞菁已被证明在有机发光二极管（OLEDs）和有机光伏器件（OPVs）中具有作为功能材料的潜力。在这里，我们综述了氯代硼次酞菁（Cl-BsubPc）的材料性能及其作为有机半导体的应用。然后，我们重点介绍了 Cl-BsubPc 以外的硼次酞菁衍生物的研究进展，并讨论了分子设计对材料性能和 BsubPc 性能的影响。最后，我们对有机电子领域中 BsubPcs 的现状进行了评论，并讨论了我们认为未来如何取得进展。
