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水溶液中金属离子路易斯酸强度的气相观点。

A gas phase perspective on the Lewis acidity of metal ions in aqueous solution.

机构信息

Department of Physical Chemistry, School of Chemistry, The University of Nottingham, University Park, Nottingham NG7 2RD, UK.

出版信息

Chem Commun (Camb). 2012 Oct 25;48(83):10292-4. doi: 10.1039/c2cc35859j.

DOI:10.1039/c2cc35859j
PMID:22983305
Abstract

A pattern of instability exhibited by solvated metal dications in the gas phase shows a remarkable correlation (covering 10 orders of magnitude) with the ability of the same metal ions to promote the release of protons in aqueous solution.

摘要

在气相中,溶剂化金属二阳离子表现出的不稳定性模式与相同金属离子在水溶液中促进质子释放的能力之间存在显著的相关性(涵盖 10 个数量级)。

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