State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P.R. China.
Chem Commun (Camb). 2012 Oct 28;48(84):10419-21. doi: 10.1039/c2cc35399g. Epub 2012 Sep 17.
A family of chiral porous metal-organic frameworks were synthesized through an unprecedented chiral transformation process only involving achiral components. This method may provide a new point of view to rationally design targeted chiral MOFs and may shed light on the symmetry breaking mechanism.
通过仅涉及非手性组分的前所未有的手性转变过程，合成了手性多孔金属有机骨架的一个家族。该方法可能为合理设计靶向手性 MOF 提供了一个新的视角，并可能揭示对称破缺机制。
