Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, P. R. China.
Chem Commun (Camb). 2012 Dec 21;48(98):12020-2. doi: 10.1039/c2cc36045d.
Studies on the reactions of 3-(tert-butyliminomethine)indole or 3-(tert-butylaminomethylene)indole with rare-earth metal amides (Me(3)Si)(2)NRE(III)(μ-Cl)Li(THF)(3) (RE = Y, Yb) led to the discovery of different reactivity patterns with isolation of novel rare-earth metal complexes having a unique indolyl-1,2-dianion in a novel η(1):(μ(2)-η(1):η(1)) bonding mode through C-H activation.
研究 3-(叔丁基亚氨基)吲哚或 3-(叔丁基亚氨基亚甲基)吲哚与稀土金属酰胺(Me(3)Si)(2)NRE(III)(μ-Cl)Li(THF)(3)（RE = Y，Yb）的反应，通过 C-H 活化，发现了不同的反应模式，并分离出具有独特吲哚-1,2-二阴离子的新型稀土金属配合物，其通过 C-H 活化以新颖的η(1):(μ(2)-η(1):η(1))键合模式键合。
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