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催化、温和、选择性的直链烷烃氧化官能化:当前的挑战。

Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges.

机构信息

Institut Charles Gerhardt Montpellier, UMR 5253 CNRS/ENSCM/UM2/UM1, 8 rue de l'Ecole Normale, 34296 Montpellier, France.

出版信息

Angew Chem Int Ed Engl. 2012 Oct 22;51(43):10712-23. doi: 10.1002/anie.201203280. Epub 2012 Sep 20.

Abstract

Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the abundance of these molecules in the environment, the possibility to transform them into higher-value compounds, such as chemicals or synthetic fuels, and the fact that, kinetically speaking, this is a difficult reaction. Numerous chemical and biological catalysts have been developed in the lasts decades for this purpose, rendering the overview over this field of chemistry difficult. After giving a definition of the ideal catalyst for alkane oxyfunctionalization, this review aims to present the catalysts available today that are closest to ideal.

摘要

由于烷烃在环境中含量丰富,将其转化为高附加值化合物(如化学品或合成燃料)具有重要意义,并且从动力学角度来看,这是一个具有挑战性的反应,因此,人们对烷烃可持续氧化的选择性催化剂有很高的需求。在过去的几十年中,已经开发出了许多化学和生物催化剂来实现这一目标,这使得对该化学领域的概述变得困难。在给出烷烃氧化官能化理想催化剂的定义后,本文旨在介绍目前最接近理想的催化剂。

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