Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, PR China.
ChemSusChem. 2012 Oct;5(10):1892-6. doi: 10.1002/cssc.201200611. Epub 2012 Sep 23.
Oxidizing aromatics: We report an operationally simple and green catalytic oxidative esterification approach that selectively converts methyl aromatics to aromatic carboxylates utilizing a highly stable, active, and reusable heterogeneous bimetallic Au-Pd catalyst and molecular oxygen as benign oxidant without requiring any additives.
我们报告了一种操作简单且绿色的催化氧化酯化方法,利用高度稳定、活性和可重复使用的多相双金属 Au-Pd 催化剂和分子氧作为良性氧化剂,选择性地将甲基芳烃转化为芳香羧酸酯,而无需任何添加剂。