Laboratory of Macromolecular and Organic Chemistry, Institute for Complex Molecular Systems, Eindhoven University of Technology, The Netherlands.
Angew Chem Int Ed Engl. 2013 Jan 2;52(1):304-9. doi: 10.1002/anie.201205085. Epub 2012 Sep 23.
The cooperative self-assembly of chiral zinc porphyrins is regulated by a photoresponsive phenylazopyridine ligand. Porphyrin stacks depolymerize into dimers upon axial ligation and the strength of the coordination is regulated by its photoinduced isomerization, which shows more than 95 % conversion ratio for both photostationary states.
手性锌卟啉通过光响应的苯并偶氮吡啶配体进行协同自组装。轴向配位后卟啉堆积物解聚成二聚体，配位强度可通过其光诱导异构化进行调节，两种光稳定态的转化率均超过 95%。
