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在微波辐射下,通过简便的方法合成芳基偶氮烟酸盐,用于聚酯纤维的染色及其生物活性谱分析。

A facile synthesis of arylazonicotinates for dyeing polyester fabrics under microwave irradiation and their biological activity profiles.

机构信息

Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait.

出版信息

Molecules. 2012 Sep 27;17(10):11495-506. doi: 10.3390/molecules171011495.

Abstract

A as textile dyes and the fastness properties of the dyed samples were measured. Most of the dyed fabrics tested displayed very good washing and perspiration fastness and series of 2-hydroxy- and 2-amino-6-substituted-5-arylazonicotinate monoazo compounds 7a-e and 9a-c were prepared via condensation of 3-oxo-3-substituted-2-arylhydrazonals 2a-e with active methylene nitriles 3a-d using microwave irradiation as an energy source. These substances were then tested moderate light fastness. Finally, the biological activity of the synthesized compounds against gram positive bacteria, gram negative bacteria and yeast were evaluated.

摘要

A 用作纺织染料,并且测量了染色样品的牢度性能。测试的大多数染色织物显示出非常好的耐洗和耐汗牢度,并且通过用微波辐射作为能量源,使 3-氧代-3-取代-2-芳基腙 2a-e 与活性亚甲基腈 3a-d 缩合,制备了一系列 2-羟基-和 2-氨基-6-取代-5-芳基偶氮化合物 7a-e 和 9a-c。然后测试这些物质的中光牢度。最后,评估了合成化合物对革兰氏阳性菌、革兰氏阴性菌和酵母的生物活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8a5/6268463/7b52de1eed28/molecules-17-11495-g003.jpg

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