Amgoune Abderrahmane, Bouhadir Ghenwa, Bourissou Didier
Laboratoire Hétérochimie Fondamentale et Appliquée, University of Toulouse, UPS, UMR CNRS 5069, 118, route de Narbonne, 31062, Toulouse Cédex 04, France.
Top Curr Chem. 2013;334:281-311. doi: 10.1007/128_2012_370.
Over the last few years, the coordination of phosphine-boranes and related Frustrated Lewis Pairs to transition metals has attracted considerable interest. These polyfunctional, ambiphilic ligands are very versatile. In particular, the Lewis acid site may participate in different ways to coordination, directly at the metal or in near periphery. These recent achievements are presented and discussed in this chapter.
在过去几年中，膦硼烷及相关受阻路易斯酸碱对与过渡金属的配位作用引起了人们的广泛关注。这些多功能、双亲性配体具有很强的通用性。特别是，路易斯酸位点可以通过不同方式参与配位，直接与金属配位或在其近邻区域配位。本章将介绍并讨论这些最新成果。
