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两种堆肥作为生物过滤去除气态还原硫化合物 (RSCs) 的过滤介质的比较研究:在工业规模上的应用。

A comparative study of two composts as filter media for the removal of gaseous reduced sulfur compounds (RSCs) by biofiltration: application at industrial scale.

机构信息

Université de Pau et des Pays de l'Adour (UPPA), Laboratoire de Thermique, Energétique et Procédés (LaTEP), Equipe Traitement des Effluents Gazeux Site de Tarbes, Département Génie des Procédés, Quartier Bastillac, 65000 Tarbes, France.

出版信息

Waste Manag. 2013 Jan;33(1):18-25. doi: 10.1016/j.wasman.2012.09.009. Epub 2012 Oct 1.

Abstract

This work presents the use of two composts as filter media for the treatment by biofiltration of odors emitted during the aerobic composting of a mixture containing sewage sludge and yard waste. The chemical analysis of the waste gas showed that the malodorous compounds at trace level were the reduced sulfur compounds (RSCs) which were dimethyl sulfide (Me(2)S), methanethiol (MeSH) and hydrogen sulfide (H(2)S). Laboratory tests for biofiltration treatment of RSCs were performed in order to compare the properties of two filter media, consisted of a mature compost with yard waste (YW) and a mixture of mature compost with sewage sludge and yard waste (SS/YW). The maximum elimination capacity (EC) values obtained with the YW mature compost as packing material were 12.5 mg m(-3)h(-1) for H(2)S, 7.9 mg m(-3)h(-1) for MeSH and 34 mg m(-3)h(-1) for Me(2)S, and the removal efficiency decreased in the order of: H(2)S>MeSH>Me(2)S. Moreover, the YW compost filter medium had a better behavior than the filter medium based on SS/YW in terms of acclimation of the microbial communities and moisture content. According to these results, a YW mature compost as packing material for an industrial biofilter were designed and this industrial biofilter was found effective under specified conditions (without inoculation and addition of water). The results showed that the maximum EC value of RSCs was 935 mg m(-3)h(-1) (100% removal efficiency, RE) for an inlet loads (IL) between 0 and 1000 mg m(-3)h(-1). Thus, YW compost medium was proven efficient for biofiltration of RSCs both at laboratory and industrial scale.

摘要

本工作采用两种堆肥作为过滤介质,通过生物过滤处理好氧堆肥过程中排放的恶臭气体,该堆肥混合物包含污水污泥和庭院废物。废气的化学分析表明,痕量的恶臭化合物是还原硫化合物(RSCs),分别为二甲硫醚(Me2S)、甲硫醇(MeSH)和硫化氢(H2S)。为了比较两种过滤介质的性能,进行了 RSCs 生物过滤处理的实验室测试,这两种过滤介质分别由含有庭院废物的成熟堆肥(YW)和含有成熟堆肥、污水污泥和庭院废物的混合物(SS/YW)组成。以 YW 成熟堆肥作为包装材料,获得的最大去除容量(EC)值分别为 12.5 mg m(-3)h(-1)(H2S)、7.9 mg m(-3)h(-1)(MeSH)和 34 mg m(-3)h(-1)(Me2S),去除效率依次为:H2S>MeSH>Me2S。此外,在微生物群落的驯化和水分含量方面,YW 堆肥过滤介质的性能优于基于 SS/YW 的过滤介质。根据这些结果,设计了一种 YW 成熟堆肥作为工业生物过滤器的包装材料,在特定条件下(不接种和不加水),该工业生物过滤器是有效的。结果表明,对于 0 至 1000 mg m(-3)h(-1)的入口负荷(IL),RSCs 的最大 EC 值为 935 mg m(-3)h(-1)(100%去除效率,RE)。因此,YW 堆肥介质在实验室和工业规模上均被证明对 RSCs 的生物过滤是有效的。

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