Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Fukuoka, 816-8580, Japan.
Dalton Trans. 2012 Nov 28;41(44):13575-7. doi: 10.1039/c2dt31168b. Epub 2012 Oct 4.
The reaction of Co(NO(3))(2)·6H(2)O and 3-benzoylpyridine with the low-spin iron(III) complex, H[Fe(III)(phen)(CN)(4)], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{Fe(III)(phen)(CN)(4)}(2)Co(II)(3-bpe)(2)] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.
Co(NO3)2·6H2O 和 3-苯甲酰基吡啶与低自旋铁(III)配合物 H[Fe(III)(phen)(CN)4]在甲醇中的反应生成了一个氰桥联的异金属链 [{Fe(III)(phen)(CN)4)}(2)Co(II)(3-bpe)(2)] (1)，它表现出链内铁磁性耦合和缓慢的双磁弛豫。
