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氢化锂(4)钛(5)氧(12)纳米线阵列用于高速率锂离子电池。

Hydrogenated Li(4)Ti(5)O(12) nanowire arrays for high rate lithium ion batteries.

机构信息

College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.

出版信息

Adv Mater. 2012 Dec 18;24(48):6502-6. doi: 10.1002/adma.201203151. Epub 2012 Oct 5.

DOI:10.1002/adma.201203151
PMID:23038151
Abstract

Self-supported Li(4) Ti(5) O(12) nanowire arrays with high conductivity architectures are designed and fabricated for application in a Li-ion battery. The Li(4) Ti(5) O(12) nanowire arrays grow directly on Ti foil by a facile solution-based method, further enhancing Li-ion storage properties by creating Ti(3+) sites through hydrogenation. This configuration ensures that every Li(4) Ti(5) O(12) nanowire participates in the fast electrochemical reaction, enabling remarkable rate performance and a long cycle life.

摘要

自支撑的 Li(4) Ti(5) O(12) 纳米线阵列具有高导电性结构,专为锂离子电池应用而设计和制造。Li(4) Ti(5) O(12) 纳米线阵列通过简便的基于溶液的方法直接在 Ti 箔上生长,通过氢化形成 Ti(3+) 位进一步增强锂离子存储性能。这种结构确保了每个 Li(4) Ti(5) O(12) 纳米线都参与快速的电化学反应,实现了出色的倍率性能和长循环寿命。

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