Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA.
J Chem Phys. 2012 Oct 7;137(13):134113. doi: 10.1063/1.4757133.
The broad success of optimally controlling quantum systems with external fields has been attributed to the favorable topology of the underlying control landscape, where the landscape is the physical observable as a function of the controls. The control landscape can be shown to contain no suboptimal trapping extrema upon satisfaction of reasonable physical assumptions, but this topological analysis does not hold when significant constraints are placed on the control resources. This work employs simulations to explore the topology and features of the control landscape for pure-state population transfer with a constrained class of control fields. The fields are parameterized in terms of a set of uniformly spaced spectral frequencies, with the associated phases acting as the controls. This restricted family of fields provides a simple illustration for assessing the impact of constraints upon seeking optimal control. Optimization results reveal that the minimum number of phase controls necessary to assure a high yield in the target state has a special dependence on the number of accessible energy levels in the quantum system, revealed from an analysis of the first- and second-order variation of the yield with respect to the controls. When an insufficient number of controls and/or a weak control fluence are employed, trapping extrema and saddle points are observed on the landscape. When the control resources are sufficiently flexible, solutions producing the globally maximal yield are found to form connected "level sets" of continuously variable control fields that preserve the yield. These optimal yield level sets are found to shrink to isolated points on the top of the landscape as the control field fluence is decreased, and further reduction of the fluence turns these points into suboptimal trapping extrema on the landscape. Although constrained control fields can come in many forms beyond the cases explored here, the behavior found in this paper is illustrative of the impacts that constraints can introduce.
最优地控制量子系统与外部场的广泛成功归因于基础控制景观的有利拓扑,其中景观是物理可观测量作为控制的函数。在满足合理物理假设的情况下,可以证明控制景观中不存在次优的捕获极值,但当对控制资源施加重大限制时,这种拓扑分析就不成立了。这项工作通过模拟来探索受约束的控制场下纯态群体转移的控制景观的拓扑和特征。这些场参数化了一组均匀间隔的光谱频率,相关相位作为控制。这种受限制的场家族提供了一个简单的示例,用于评估约束对寻求最优控制的影响。优化结果表明,为确保在目标状态下具有高产量所需的相位控制的最小数量具有对量子系统中可访问能级数量的特殊依赖性,从产量对控制的一阶和二阶变化的分析中可以看出。当控制资源不足或控制强度较弱时,在景观上会观察到捕获极值和鞍点。当控制资源足够灵活时,产生全局最大产量的解决方案被发现形成连续可变控制场的连续“水平集”,这些场保持产量。随着控制场强度的降低,这些最优产量水平集在景观顶部收缩为孤立点,而进一步降低强度会将这些点转化为景观上的次优捕获极值。尽管约束控制场可以有许多形式,超出本文所探索的情况,但本文发现的行为说明了约束可能引入的影响。