Moore Tibbetts Katharine, Rabitz Herschel
Department of Chemistry, Temple University, Philadelphia, PA, USA.
Phys Chem Chem Phys. 2015 Feb 7;17(5):3164-78. doi: 10.1039/c4cp04792c. Epub 2014 Dec 17.
The growing success of controlling the dynamics of quantum systems has been ascribed to the favorable topology of the quantum control landscape, which represents the physical observable as a function of the control field. The landscape contains no suboptimal trapping extrema when reasonable physical assumptions are satisfied, including that no significant constraints are placed on the control resources. A topic of prime interest is understanding the effects of control field constraints on the apparent landscape topology, as constraints on control resources are inevitable in the laboratory. This work particularly explores the effects of constraining the control field fluence on the topology and features of the control landscape for pure-state population transfer in a two-level system through numerical simulations, where unit probability population transfer in the system is only accessible in the strong coupling regime within the model explored here. With the fluence and three phase variables used for optimization, no local optima are found on the landscape, although saddle features are widespread at low fluence values. Global landscape optima are found to exist at two disconnected regions of the fluence that possess distinct topologies and structures. Broad scale connected optimal level sets are found when the fluence is sufficiently large, while the connectivity is reduced as the fluence becomes more constrained. These results suggest that seeking optimal fields with constrained fluence or other resources may encounter complex landscape features, calling for sophisticated algorithms that can efficiently find optimal controls.
量子系统动力学控制方面日益增长的成功归因于量子控制景观的有利拓扑结构,该结构将物理可观测量表示为控制场的函数。当满足合理的物理假设时,包括对控制资源没有显著限制,该景观不包含次优陷阱极值。一个主要感兴趣的话题是理解控制场约束对表观景观拓扑结构的影响,因为在实验室中控制资源的约束是不可避免的。这项工作特别通过数值模拟探索了在二能级系统中,约束控制场通量对纯态布居转移控制景观的拓扑结构和特征的影响,在此探索的模型中,系统中的单位概率布居转移仅在强耦合 regime 内可达。对于用于优化的通量和三个相位变量,在景观上未发现局部最优解,尽管在低通量值时鞍点特征普遍存在。发现全局景观最优解存在于通量的两个不相连区域,这些区域具有不同的拓扑结构和特征。当通量足够大时,会发现宽尺度的连通最优水平集,而随着通量受到的约束增加,连通性会降低。这些结果表明,寻找具有受限通量或其他资源的最优场可能会遇到复杂的景观特征,这需要能够有效找到最优控制的复杂算法。