Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan.
Chem Commun (Camb). 2012 Nov 21;48(90):11124-6. doi: 10.1039/c2cc35105f. Epub 2012 Oct 8.
The structural changes in a bicontinuous microemulsion gel system in a sol-gel state were elucidated via determination of the apparent diffusion coefficients, which were estimated electrochemically. The temperature dependence of D(app) in the micro oil phase or the saline phase revealed complementary hysteresis, which occurred as a result of formation of a gel network and subsequent mesoscopic phase separation.
通过电化学测定表观扩散系数，阐明了溶胶-凝胶状态下双连续微乳液凝胶体系的结构变化。微油相或盐相中的 D(app) 的温度依赖性呈现互补滞后现象，这是由于凝胶网络的形成和随后的介观相分离所致。
