钯催化的环己酮亚胺的有氧脱氢芳构化反应生成芳胺。
Palladium-catalyzed aerobic dehydrogenative aromatization of cyclohexanone imines to arylamines.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
出版信息
Org Lett. 2012 Nov 2;14(21):5488-91. doi: 10.1021/ol302568b. Epub 2012 Oct 16.
PMID:23072451
Abstract
Dehydrogenative aromatization of cyclohexanone imines to arylamines has been achieved using a palladium catalyst under aerobic conditions. The reaction is applicable to a variety of imines that are either preformed or generated in situ from cyclohexanone derivatives and aryl or alkylamines.
摘要
在有氧条件下，使用钯催化剂实现了环己酮亚胺的脱氢芳构化为芳胺。该反应适用于各种亚胺，这些亚胺可以是预先制备的，也可以是由环己酮衍生物和芳基或烷基胺原位生成的。
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