3D MOFs 包含三角双锥 Ln5 簇作为节点：大磁热效应和缓慢的磁弛豫行为。
3 D MOFs containing trigonal bipyramidal Ln5 clusters as nodes: large magnetocaloric effect and slow magnetic relaxation behavior.
机构信息
Department of Chemistry, Key Laboratory of Advanced Energy Material Chemistry MOE and TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, PR China.
出版信息
Chemistry. 2012 Nov 19;18(47):15086-91. doi: 10.1002/chem.201202412. Epub 2012 Oct 18.
Two 3D heterometal-organic frameworks based on infrequent trigonal bipyramidal Ln(5) clusters as nodes were structurally and magnetically characterized (Ln=Gd (1), Dy (2)). The results indicate large MCE of up to 30.7 J kg(-1) K(-1) in 1 and slow magnetic relaxation behavior in 2. Expectedly, constructing 3D MOFs based on multinuclear clusters as nodes may will be a new strategy for achieving large -ΔS(m). Additionally, compound 1 exhibits high thermal and solvent stabilities, providing a favorable foundation for realistic applications.
基于罕见的三角双锥 Ln(5) 簇作为节点，构建了两个 3D 异金属有机骨架，并对其结构和磁性进行了表征（Ln=Gd（1），Dy（2））。结果表明，1 中具有高达 30.7 J kg-1 K-1 的大磁热效应，2 中具有缓慢的磁弛豫行为。预期，基于多核簇作为节点构建 3D MOFs 将是实现大 -ΔS(m) 的一种新策略。此外，化合物 1 表现出高的热稳定性和溶剂稳定性，为实际应用提供了有利的基础。
Zotero 插件