Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis-(triphenyl-phosphane-κP)copper(I) methanol monosolvate.
作者信息
Jiang Yu-Han, Qiu Qi-Ming, Jiang Rui-Xia, Huang Xu, Jin Qiong-Hua
机构信息
Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1295. doi: 10.1107/S1600536812039165. Epub 2012 Sep 26.
Abstract
In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra-hedral, defined by two P atoms of two triphenyl-phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol-ecules and the methanol solvent mol-ecules are connected via N-H⋯O and O-H⋯I hydrogen bonds, forming a chain along [010]. An intra-molecular N-H⋯I hydrogen bond is also observed.
摘要
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