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生物柴油成分的微波介电性能研究。

Investigation of microwave dielectric properties of biodiesel components.

机构信息

Department of Biological and Agricultural Engineering, Louisiana State University Agricultural Center, Baton Rouge, LA 70803, United States.

出版信息

Bioresour Technol. 2013 Jan;127:165-74. doi: 10.1016/j.biortech.2012.10.008. Epub 2012 Oct 17.

Abstract

Advanced microwave technology has the potential to significantly enhance the biodiesel production process. Knowledge of dielectric properties of materials plays a major role in microwave design for any process. Dielectric properties (ε' and ε") of biodiesel precursors: soybean oil, alcohols and catalyst and their different mixtures were measured using a vector network analyzer and a slim probe in an open ended coaxial probe method at four different temperatures (30, 45, 60 and 75 °C) and in the frequency range of 280 MHz to 4.5 GHz. Results indicate that the microwave dielectric properties depend significantly on both temperature and frequency. Addition of catalyst significantly affected the dielectric properties. Dielectric properties behaved differently when oil, alcohol and catalyst was mixed at room temperature before heating and when the oil and the alcohol catalyst mixture was heated separately to a pre-determined temperature before mixing. These results can be used in designing microwave based transesterification system.

摘要

先进的微波技术有可能极大地提高生物柴油的生产工艺。在任何工艺的微波设计中,材料的介电性能知识都起着重要的作用。使用矢量网络分析仪和在开放式同轴探头法中的 slim 探头,在四个不同的温度(30、45、60 和 75°C)和频率范围(280 MHz 至 4.5 GHz)下,测量了生物柴油前体(大豆油、醇类和催化剂)及其不同混合物的介电性能(ε'和ε")。结果表明,微波介电性能显著取决于温度和频率。催化剂的添加显著影响了介电性能。当在加热前将油、醇和催化剂在室温下混合,以及当将油和醇催化剂混合物分别加热到预定温度然后再混合时,介电性能表现出不同的行为。这些结果可用于设计基于微波的酯交换系统。

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