近期的 Reformatsky-Claisen 重排反应进展。
Recent developments in the Reformatsky-Claisen rearrangement.
机构信息
Graduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan.
出版信息
Molecules. 2012 Nov 30;17(12):14249-59. doi: 10.3390/molecules171214249.
The rearrangement of allyl a-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized so often. In this article, we will provide an overview of recent advances in the Reformatsky-Claisen rearrangement field, including the In-mediated Reformatsky-Claisen rearrangement we have recently developed.
烯丙基α-溴代乙酸酯与锌粉的重排反应被称为 Reformatsky-Claisen 重排反应。虽然 Ireland-Claisen 重排反应已被广泛用于合成各种天然产物，但 Zn 介导的 Reformatsky-Claisen 重排反应并不常用。本文将综述 Reformatsky-Claisen 重排反应领域的最新进展，包括我们最近开发的 In 介导的 Reformatsky-Claisen 重排反应。
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