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开放系统最大熵原理的微正则起源。

Microcanonical origin of the maximum entropy principle for open systems.

作者信息

Lee Julian, Pressé Steve

机构信息

Department of Bioinformatics and Life Science, Soongsil University, Seoul 156-743, Korea.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Oct;86(4 Pt 1):041126. doi: 10.1103/PhysRevE.86.041126. Epub 2012 Oct 15.

Abstract

There are two distinct approaches for deriving the canonical ensemble. The canonical ensemble either follows as a special limit of the microcanonical ensemble or alternatively follows from the maximum entropy principle. We show the equivalence of these two approaches by applying the maximum entropy formulation to a closed universe consisting of an open system plus bath. We show that the target function for deriving the canonical distribution emerges as a natural consequence of partial maximization of the entropy over the bath degrees of freedom alone. By extending this mathematical formalism to dynamical paths rather than equilibrium ensembles, the result provides an alternative justification for the principle of path entropy maximization as well.

摘要

推导正则系综有两种不同的方法。正则系综要么作为微正则系综的一个特殊极限出现,要么可由最大熵原理得出。我们通过将最大熵公式应用于一个由开放系统加热库组成的封闭宇宙来证明这两种方法的等效性。我们表明,用于推导正则分布的目标函数是仅对热库自由度进行熵的部分最大化的自然结果。通过将这种数学形式扩展到动力学路径而非平衡系综,该结果也为路径熵最大化原理提供了另一种证明。

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