Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Shandong University, Jinan 250100, PR China.
Carbohydr Polym. 2013 Jan 30;92(1):516-22. doi: 10.1016/j.carbpol.2012.09.082. Epub 2012 Oct 13.
Rheological properties of welan gum and xanthan gum solutions have been characterized systematically at various concentrations, temperatures and salinities. It is found that the viscoelasticity of welan gum is higher than that of xanthan gum at the same condition though the molecular weight of welan gum is lower. In view of this, welan gum will make a good performance in enhanced oil recovery, especially in high temperature and high salinity reservoirs. Network structure can be formed in solutions of welan gum and xanthan gum for the dynamic modulus has exponential relationship with the concentration. Moreover, the molecular aggregates of welan gum adopt a different arrangement with that of xanthan gum, adjacent double helices of welan gum arrange in parallel as the zipper model. The structure formed by zipper model is still stable in high temperature and high salinity.
已系统地研究了不同浓度、温度和盐度下黄原胶和瓜尔胶溶液的流变性能。尽管黄原胶的分子量较低,但在相同条件下,黄原胶的粘弹性高于黄原胶。鉴于此,黄原胶在提高采收率方面将表现良好,特别是在高温高盐油藏中。黄原胶和瓜尔胶溶液中可以形成网络结构,因为动态模量与浓度呈指数关系。此外,黄原胶的分子聚集体采用与黄原胶不同的排列方式,黄原胶的相邻双螺旋平行排列,呈拉链式模型。拉链式模型形成的结构在高温高盐条件下仍然稳定。