Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
Dalton Trans. 2013 Apr 7;42(13):4337-9. doi: 10.1039/c2dt32645k.
Preparation of POSS-min-DS, an octaimidazolium-based polyhedral oligomeric silsesquioxanes (POSS) room temperature ionic liquid, by an ion-exchange reaction between POSS and sodium dodecyl sulfate was reported. Octaimidazolium-based POSS was synthesized with more than 98% yield within 3 h. POSS-min-DS and octaimidazolium-based POSS were confirmed by (1)H, (13)C, and (29)Si NMR, FT-IR and elemental analysis.
通过 POSS 与十二烷基硫酸钠之间的离子交换反应，制备了八咪唑基笼型倍半硅氧烷（POSS）室温离子液体 POSS-min-DS。八咪唑基 POSS 在 3 小时内以超过 98%的收率合成。通过（1）H、（13）C 和（29）Si NMR、FT-IR 和元素分析证实了 POSS-min-DS 和八咪唑基 POSS 的存在。
