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碳纳米管电子学——向前迈进。

Carbon nanotube electronics--moving forward.

机构信息

Electrical Engineering and Computer Sciences, University of California, Berkeley, CA 94720, USA.

出版信息

Chem Soc Rev. 2013 Apr 7;42(7):2592-609. doi: 10.1039/c2cs35325c.

Abstract

Single-walled carbon nanotubes (SWNTs) possess fascinating electrical properties and offer new entries into a wide range of novel electronic applications that are unattainable with conventional Si-based devices. The field initially focused on the use of individual or parallel arrays of nanotubes as the channel material for ultra-scaled nanoelectronic devices. However, the challenge in the deterministic assembly has proven to be a major technological barrier. In recent years, solution deposition of semiconductor-enriched SWNT networks has been actively explored for high performance and uniform thin-film transistors (TFTs) on mechanically rigid and flexible substrates. This presents a unique niche for nanotube electronics by overcoming their limitations and taking full advantage of their superb chemical and physical properties. This review focuses on the large-area processing and electronic properties of SWNT TFTs. A wide range of applications in conformal integrated circuits, radio-frequency electronics, artificial skin sensors, and displays are discussed--with emphasis on large-area systems where nm-scale accuracy in the assembly of nanotubes is not required. The demonstrations show SWNTs' immense promise as a low-cost and scalable TFT technology for nonconventional electronic systems with excellent device performances.

摘要

单壁碳纳米管(SWNTs)具有迷人的电学性能,为各种新型电子应用提供了新的途径,而这些应用是传统的基于 Si 的器件无法实现的。该领域最初专注于使用单个或平行排列的纳米管作为超小型纳米电子器件的通道材料。然而,在确定组装方面的挑战已被证明是一个主要的技术障碍。近年来,人们积极探索通过溶液沉积半导体富集的 SWNT 网络,以在机械刚性和柔性衬底上实现高性能和均匀的薄膜晶体管(TFT)。这通过克服其局限性并充分利用其优异的化学和物理特性,为纳米管电子学提供了一个独特的利基市场。本综述重点介绍 SWNT TFT 的大面积处理和电子特性。讨论了其在共形集成电路、射频电子、人造皮肤传感器和显示器等广泛应用领域的应用——重点是大面积系统,在这些系统中,不需要纳米级精度的纳米管组装。这些演示表明,SWNTs 作为一种低成本、可扩展的 TFT 技术,具有出色的器件性能,非常有希望用于具有优异器件性能的非常规电子系统。

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