Department of Materials Science and Engineering, Faculty of Engineering, NUSNNI-NanoCore, National University of Singapore, 117576, Singapore.
Phys Chem Chem Phys. 2013 Feb 14;15(6):1793-7. doi: 10.1039/c2cp44466f. Epub 2012 Dec 21.
Reversible chemical delithiation/lithiation of LiFePO(4) was successfully demonstrated using ferrocene derivatives, based on which a novel energy storage system--the redox flow lithium-ion battery (RFLB), was devised by integrating the operation flexibility of a redox flow battery and high energy density of a lithium-ion battery. Distinct from the recent semi-solid lithium rechargeable flow battery, the energy storage materials of RFLB stored in separate energy tanks remain stationary upon operation, giving us a fresh perspective on building large-scale energy storage systems with higher energy density and improved safety.
使用二茂铁衍生物成功地证明了 LiFePO(4) 的可逆化学脱锂/锂化。在此基础上，通过整合氧化还原流电池的操作灵活性和锂离子电池的高能量密度，设计了一种新型储能系统——氧化还原流锂离子电池 (RFLB)。与最近的半固态锂可再充电流电池不同，RFLB 的储能材料在运行时储存在单独的储能罐中保持静止，这为我们构建具有更高能量密度和更高安全性的大型储能系统提供了新的视角。
