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开发新型电位传感器,用于测定食品中亚硫酸盐染料浓度。

Development of novel potentiometric sensors for determination of tartrazine dye concentration in foodstuff products.

机构信息

Chemistry Department, College of Sciences, Al-Aqsa University, Gaza, Palestine.

出版信息

Food Chem. 2013 May 1;138(1):126-32. doi: 10.1016/j.foodchem.2012.10.048. Epub 2012 Nov 8.

Abstract

Tartrazine dye Na(3)TZ in foodstuff products was determined by a new modified carbon paste electrode, encoded sensor A, and a coated silver wire electrode, encoded sensor B, based on tartrazine TZ- cetryltrimethyl ammoniumbromide CTAB as a chemical modifier TZ-CTA. The electrodes exhibit the following characteristics listed respectively: a Nernstian slope of 17.9±0.5 and 19.4±0.2 mV/decade for tartrazine ion over a wide concentration range from 4.3×10(-7) to 1.0×10(-2) and 1.1×10(-7) to 1.0×10(-2) M. The lower detection limits: 3.2×10(-7) and 5.5×10(-8) M. Short response time (5-8 s) over the pH range 3.8-7.7 and 4.2-8.1. The proposed sensors display significantly high selectivity for TZ ion over a wide variety of sugars, some anions, common organic, inorganic compounds and additives. The developed electrodes were applied to the potentiometric determination of tartrazine ion in different kinds of foodstuffs: solid jelly (strawberry and custard) powder samples and soft drink (orange) samples with satisfactory results.

摘要

食品中食用黄色素(Na(3)TZ)的测定采用新型修饰碳糊电极(编码传感器 A)和涂覆银丝电极(编码传感器 B),以食用黄色素 TZ-十六烷基三甲基溴化铵(CTAB)作为化学修饰剂 TZ-CTA。电极具有以下特点:在宽浓度范围内(4.3×10(-7)到 1.0×10(-2)和 1.1×10(-7)到 1.0×10(-2) M),对食用黄色素离子呈现出 17.9±0.5 和 19.4±0.2 mV/decade 的 Nernst 斜率。检测下限分别为 3.2×10(-7)和 5.5×10(-8) M。在 pH 值 3.8-7.7 和 4.2-8.1 范围内,响应时间短(5-8 s)。与多种糖类、阴离子、常见有机和无机化合物及添加剂相比,该传感器对 TZ 离子具有显著的高选择性。所开发的电极用于不同种类的食品中食用黄色素离子的电位测定,如固体果冻(草莓和奶油)粉末样品和软饮料(橙汁)样品,结果令人满意。

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