Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
Chem Commun (Camb). 2013 Feb 4;49(11):1100-2. doi: 10.1039/c2cc38575a.
The morphological evolution of PANI helixes was achieved without the use of chiral dopants, but by a facile process through the generation of onion-like multi-lamellar vesicles used as a novel soft-template and a liquid crystal acting as a promoter for PANI polymerization and self-assembly, which is a breakthrough for the synthesis of helical structures.
无手性掺杂剂,通过简便的方法制备洋葱状多层层状囊泡作为一种新型软模板,利用向列相液晶作为促进剂诱导 PANI 聚合和自组装来实现 PANI 螺旋结构的形态演变,这是螺旋结构合成的突破。