Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong 250100, China.
Dalton Trans. 2013 Mar 14;42(10):3528-32. doi: 10.1039/c2dt32375c. Epub 2013 Jan 2.
A novel octanuclear Ag(I)(6)-Zn(II)(2) heterometallic aggregate, (NH(4))(2){[Zn(2)(phen)(2)(H(2)O)(4)][Ag(6)(mna)(6)]}·2H(2)O·2CH(3)CH(2)OH (1, H(2)mna = 2-mercaptonicotinic acid, phen = 1,10-phenanthroline), was stepwisely obtained based on a hexanuclear silver(i) metalloligand using a liquid-liquid diffusion method. It is an exceedingly rare example that exhibits interesting temperature dependent photoluminescence behaviors, including gradual changes in energy and intensity upon cooling.
一种新型的八核银（I）（6）-锌（II）（2）杂金属聚集体，（NH（4））（2）{[Zn（2）（phen）（2）（H（2）O）（4）][Ag（6）（mna）（6）]}·2H（2）O·2CH（3）CH（2）OH（1，H（2）mna = 2-巯基烟酸，phen = 1,10-菲咯啉），是通过使用液-液扩散方法，以六核银（I）金属配合物为基础逐步得到的。这是一个非常罕见的例子，它表现出有趣的温度依赖光致发光行为，包括冷却时能量和强度的逐渐变化。
