Kim Tae Ho, Moon Suk-Hee, Kim Jineun, Park Ki-Min
Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Republic of Korea.
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):o3237. doi: 10.1107/S1600536812044248. Epub 2012 Oct 31.
IN THE TITLE COMPOUND [SYSTEMATIC NAME: (3-chloro-2,6-dimeth-oxy-phen-yl)(eth-oxy-imino)-methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro-dimeth-oxy-phenyl rings are linked by the eth-oxy-imino-methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C-H⋯O and C-H⋯Cl hydrogen bonds between the phenyl and chloro-dimeth-oxy-phenyl rings generate R(2) (2)(8) rings which link the mol-ecules into zigzag chains along the b axis. Additional C-H⋯O contacts, together with weak inter-molecular C-H⋯π inter-actions, further link the mol-ecules into a three-dimensional network.
在标题化合物[系统名称：(3-氯-2,6-二甲氧基苯基)(乙氧基-亚氨基)-甲基苯甲酸酯]，C(18)H(18)ClNO(5)中，苯基和氯代二甲氧基苯基环通过乙氧基-亚氨基-甲基苯甲酸酯体系相连，使得它们彼此几乎垂直，它们之间的二面角为85.72 (9)°。在晶体中，苯基和氯代二甲氧基苯基环之间的C-H⋯O和C-H⋯Cl氢键形成R(2) (2)(8)环，这些环将分子沿b轴连接成锯齿链。额外的C-H⋯O接触，连同弱的分子间C-H⋯π相互作用，进一步将分子连接成三维网络。
