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花生壳活性炭对结晶紫的吸附动力学、等温线和热力学研究。

Kinetic, isotherm and thermodynamic studies of the adsorption of crystal violet by activated carbon from peanut shells.

机构信息

Department of Chemistry, Langfang Teachers' College, Langfang, Hebei, China.

出版信息

Water Sci Technol. 2013;67(4):737-44. doi: 10.2166/wst.2012.605.

Abstract

The adsorption of crystal violet dye from aqueous solutions onto an activated carbon prepared from peanut shells was analyzed in this study. The effects of particle size, initial concentration, time and temperature on crystal violet removal were studied in batch experiments. Experimental results showed that the adsorption equilibrium was achieved within 100 min for all studied concentrations. Analysis of adsorption results showed that the adsorption isotherms could be well fitted to the Langmuir model. Kinetic parameters, rate constants, equilibrium adsorption capacities and related correlation coefficients for pseudo first-order and second-order kinetic models were calculated and discussed. The results revealed that the adsorption kinetics was in good agreement with the pseudo second-order equation. Thermodynamic parameters such as the change of Gibbs free energy (ΔG°), change of enthalpy (ΔH°) and change of entropy (ΔS°) have also been determined and it has been found that the adsorption process should be spontaneous, endothermic and physisorption in nature.

摘要

本研究分析了从水溶液中用花生壳制备的活性炭对结晶紫染料的吸附。在批量实验中研究了粒径、初始浓度、时间和温度对结晶紫去除的影响。实验结果表明,所有研究浓度的吸附平衡在 100 分钟内达到。吸附结果分析表明,吸附等温线可以很好地符合朗缪尔模型。计算并讨论了拟一级和拟二级动力学模型的动力学参数、速率常数、平衡吸附容量和相关相关系数。结果表明,吸附动力学与拟二级方程吻合较好。还确定了热力学参数,如吉布斯自由能变化 (ΔG°)、焓变化 (ΔH°) 和熵变化 (ΔS°),发现吸附过程应该是自发的、吸热的和物理吸附的。

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