过渡金属催化的通过双重 C(乙烯基)-H 键活化的 C(乙烯基)-C(乙烯基)键形成。
Transition metal-catalyzed C(vinyl)-C(vinyl) bond formation via double C(vinyl)-H bond activation.
机构信息
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou Gansu 730000, PR China.
出版信息
Chem Soc Rev. 2013 Apr 21;42(8):3253-60. doi: 10.1039/c2cs35445d.
PMID:23318664
Abstract
Transition metal-catalyzed oxidative dehydrogenative coupling reactions of Caryl-H bonds with Cvinyl-H bonds to generate a Caryl-Cvinyl bonds have been well developed in recent decades. However, only a few studies have focused on the direct Cvinyl-Cvinyl bond formation via double Cvinyl-H bond activation. Recent developments in this active area have been highlighted in this tutorial review.
摘要
过渡金属催化的芳基-碳氢键与碳-碳双键氢的氧化脱氢偶联反应生成芳基-碳碳双键在最近几十年得到了很好的发展。然而，只有少数研究集中在通过双碳-碳双键氢活化直接形成碳-碳双键键上。本综述重点介绍了这一活跃领域的最新发展。
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