Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.
ChemSusChem. 2013 Mar;6(3):417-20. doi: 10.1002/cssc.201200759. Epub 2013 Jan 15.
Forget about CO! Carbonylations are among the most important homogeneously catalyzed reactions in the chemical industry, but typically require carbon monoxide. Instead, straightforward and efficient alkoxycarbonylations of olefins can proceed with alkyl formates in the presence of a specific palladium catalyst. Aromatic, terminal aliphatic, and internal olefins are carbonylated to give industrially important linear esters at low catalyst loadings.
忘记 CO 吧！羰基化反应是化学工业中最重要的均相催化反应之一，但通常需要一氧化碳。相反，在特定钯催化剂的存在下，烯烃可以使用简单高效的甲酸烷基酯进行烷氧基羰基化反应。芳族、末端脂肪族和内部烯烃被羰基化，以低催化剂负载量得到工业上重要的线性酯。
