unprecedented Mn(III)4Dy(III)3 和 Mn(III)4Dy(III)5 簇中缓慢的磁化弛豫来自于 N-水杨醛-o-邻氨基酚的使用。
Slow magnetization relaxation in unprecedented Mn(III)4Dy(III)3 and Mn(III)4Dy(III)5 clusters from the use of N-salicylidene-o-aminophenol.
机构信息
Department of Chemistry, Brock University, L2S 3A1 St. Catharines, Ontario, Canada.
出版信息
Inorg Chem. 2013 Feb 4;52(3):1179-81. doi: 10.1021/ic302505p. Epub 2013 Jan 16.
PMID:23323592
Abstract
The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to Mn(III)(4)Dy(III)(5) and Mn(III)(4)Dy(III)(3) clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.
摘要
N-水杨叉基邻氨基酚在 3d/4f 化学中的首次应用导致了具有前所未有的金属拓扑和化学计量的 Mn(III)(4)Dy(III)(5)和 Mn(III)(4)Dy(III)(3)簇合物; 这两种化合物都表现出反相同步信号，表明单个分子磁体的缓慢磁化弛豫。
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