ACS Appl Mater Interfaces. 2013 Feb;5(3):485-8. doi: 10.1021/am302541f. Epub 2013 Jan 30.
Superhydrophobicity and self-cleaning require a combination of surface topography and low-energy surfaces, where mechanical damage of the topography or contamination with oils lead to loss of the nonwetting properties. We show that such vulnerability can be solved by superamphiphobic (i.e., both superhydrophobic and superoleophobic) surfactant-coated aerogel surfaces. Using silica aerogels as model materials, the self-similar network structure allows fresh re-entrant surface topographies even after removal of the uppermost layer upon mechanical abrasion, and superoleophobicity suppresses oil contamination. Given the recent progress toward mechanically strong aerogels, we foresee that the concept can open routes for robust self-cleaning coating technologies.
超疏水性和自清洁性需要表面形貌和低能表面的结合,而表面形貌的机械损伤或被油污染会导致非润湿特性的丧失。我们表明,这种脆弱性可以通过超憎水(即超疏水和超疏油)表面活性剂涂层气凝胶表面来解决。使用二氧化硅气凝胶作为模型材料,自相似的网络结构允许在机械磨损去除最上层后重新形成新的凹入表面形貌,并且超疏油性抑制了油的污染。鉴于最近在机械强度气凝胶方面的进展,我们预计这一概念将为强大的自清洁涂层技术开辟道路。