通过 NMR 自旋-自旋耦合看弱 Te-Te 相互作用。
Weak Te,Te interactions through the looking glass of NMR spin-spin coupling.
机构信息
EaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST, UK.
出版信息
Angew Chem Int Ed Engl. 2013 Feb 25;52(9):2495-8. doi: 10.1002/anie.201205998. Epub 2013 Jan 23.
Abstract
Across the bay: J((125)Te, (125)Te) spin-spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems.
摘要
湾对岸
J((125)Te, (125)Te) 自旋-自旋偶合是一种对 1,8-取代萘碲衍生物的电子和几何结构非常敏感的探针。这种偶合与这些体系中多中心键的形成有关。
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