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溶剂处理增强高效聚合物太阳能电池。

High-efficiency polymer solar cells enhanced by solvent treatment.

机构信息

Center for Polymers and Organic Solids, University of California, Santa Barbara, Santa Barbara, CA 93106, USA.

出版信息

Adv Mater. 2013 Mar 20;25(11):1646-52. doi: 10.1002/adma.201204306. Epub 2013 Jan 28.

DOI:10.1002/adma.201204306
PMID:23355303
Abstract

A significant enhancement of efficiency in thieno[3,4-b]-thiophene/benzodithiophene:[6,6]-phenyl C71-butyric acid methyl ester (PTB7:PC70 BM) solar cells can be achieved by methanol treatment. The effects of methanol treatment are shown in an improvement of built-in voltage, a decrease in series resistance, an enhanced charge-transport property, an accelerated and enlarged charge extraction, and a reduced charge recombination, which induce a simultaneous enhancement in open-circuit voltage (Voc), short-circuit current (Jsc), and fill factor (FF) in the devices.

摘要

甲醇处理可显著提高噻吩[3,4-b]噻吩/苯并二噻吩[6,6]-苯基 C71-丁酸甲酯(PTB7:PC70BM)太阳能电池的效率。甲醇处理的效果表现为内置电压提高、串联电阻降低、电荷输运性能增强、电荷提取加速和扩大、以及电荷复合减少,这导致器件的开路电压(Voc)、短路电流(Jsc)和填充因子(FF)同时提高。

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