Institut Parisien de Chimie Moléculaire (UMR CNRS 7201)-FR 2769, Université Pierre et Marie Curie, Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris, France.
Org Lett. 2013 Feb 15;15(4):748-51. doi: 10.1021/ol3033048. Epub 2013 Jan 29.
Spirosilane derivatives have been investigated as fluoride sensors. The reactions between these compounds and different fluoride sources, which resulted in structural alterations, have been monitored and quantified by UV and fluorescence spectroscopy. The high selectivity of these probes for fluoride ions has been demonstrated in either organic or aqueous media.
硅氮烷衍生物已被研究作为氟化物传感器。这些化合物与不同氟源的反应导致结构发生变化,通过紫外和荧光光谱对其进行了监测和定量。这些探针在有机或水相中对氟离子具有高选择性。